STEREOCHEMISTRY OF THERMAL [2+2] CYCLOADDITION OF DISILENE WITH ACETYLENE

STEREOCHEMISTRY OF THERMAL [2+2] CYCLOADDITION OF DISILENE WITH ACETYLENE
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二硅烯与乙炔的热[2 2]环加成反应的立体化学

DOI:
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发表时间:
1985
期刊:
影响因子:
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通讯作者:
H. Sakurai
H. Sakurai
中科院分区:
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文献类型:
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作者:
Y. Nakadaira;R. Sato;H. Sakurai

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The reaction of diphenylacetylene with thermally generated cis- and trans-1,2-dimethyl-1,2-diphenyldisilene at 300 °C gave a mixture of the [2+2] cycloadducts in a stereoselective but not completely stereospecific manner. A stepwise radical mechanism is suggested.