Conjugated Microporous Polymers
Conjugated Microporous Polymers
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DOI：
10.1002/adma.200801971
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发表时间：
2009-03-26
影响因子：
29.4
通讯作者：
Cooper, Andrew I.
中科院分区：
文献类型：
--
作者：
Cooper, Andrew I.
共轭微孔聚合物由于在干燥状态下具有高比表面积和与有机电子相关的物理性质而引起人们的极大兴趣。最近的一系列报道表明，聚芳乙炔S(PAEs)、聚苯二烯S、聚苯乙炔、聚对苯撑S、聚硅烷、聚苯胺和多三嗪等材料可以形成微孔网络，在某些情况下，表观Brunauer-Emmett-Teller表面积超过1000m(2)g(-1)。微孔大小和表面积可以在无定形PAE聚合物和共聚物中合成微调，这在以前被认为是有序结晶材料的保留，如金属有机骨架。我们在这篇研究新闻文章中回顾了我们小组和其他人取得的最新进展，并特别强调了这些材料未来可能的应用。
Conjugated microporous polymers are of great interest because they have potential to combine high surface areas in the dry state with physical properties relevant to organic electronics. A series of recent reports has shown that materials such as poly(aryleneethynylene)s (PAEs), poly(phenylene butadiynylene)s, poly(phenylene vinylene), poly(p-phenylene)s, polysilanes, polyanilines, and polytriazines can be produced as microporous networks with apparent Brunauer-Emmett-Teller surface areas of more than 1000 m(2) g(-1) in some cases. Micropore size and surface area can be synthetically fine tuned in amorphous PAE polymers and copolymers, something which was previously thought to be the preserve of ordered crystalline materials such as metal organic frameworks. We review in this Research News article recent progress made by our group and others with particular emphasis on the possible future applications of these materials.