Understanding individual defects in CdTe thin-film solar cells via STEM: From atomic structure to electrical activity

Understanding individual defects in CdTe thin-film solar cells via STEM: From atomic structure to electrical activity
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DOI:
10.1016/j.mssp.2016.06.017
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发表时间:
2017-07
影响因子:
4.1
通讯作者:
Chen Li;J. Poplawsky;Yanfa Yan;S. Pennycook
Chen Li;J. Poplawsky;Yanfa Yan;S. Pennycook
中科院分区:
工程技术3区
文献类型:
--
作者:
Chen Li;J. Poplawsky;Yanfa Yan;S. Pennycook

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在这里,我们回顾了CdTe太阳能电池中的一系列缺陷的结构-性能相关性的系统研究。各种实验方法,包括像差校正扫描透射电子显微镜,电子能量损失谱,能量色散X射线光谱,和电子束诱导电流已与密度泛函理论相结合。本研究追踪个别缺陷的结构和电活动之间的联系,包括晶粒内的部分位错,晶界和CdTe/CdS界面。对结构-性质相关性的物理起源的解释提供了见解,应该进一步发展未来的CdTe太阳能电池。
Here we review a systematic study of the structure-property correlations of a series of defects in CdTe solar cells. A variety of experimental methods, including aberration-corrected scanning transmission electron microscopy, electron energy loss spectroscopy, energy dispersive X-ray spectroscopy, and electron-beam-induced current have been combined with density-functional theory. The research traces the connections between the structures and electrical activities of individual defects including intra-grain partial dislocations, grain boundaries and the CdTe/CdS interface. The interpretations of the physical origin underlying the structure-property correlation provide insights that should further the development of future CdTe solar cells.