Three novel silver complexes with ligand-unsupported argentophilic interactions and their luminescent properties.
Three novel silver complexes with ligand-unsupported argentophilic interactions and their luminescent properties.
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DOI：
10.1021/ic0601539
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发表时间：
2006-05
影响因子：
4.6
通讯作者：
Xi Liu;G. Guo;Ming‐Lai Fu;Xue-Hui Liu;Ming‐Sheng Wang;Jin-shun Huang
中科院分区：
文献类型：
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作者：
Xi Liu;G. Guo;Ming‐Lai Fu;Xue-Hui Liu;Ming‐Sheng Wang;Jin-shun Huang
用溶剂热法合成了三个新型的银配合物[AG5(CN)5(Bipy)2]n(1)，[Ag5(CN)5(Bipy)2]n(1)，[AG5(SCN)4(CN)(Bipy)2]n(2)，[AG5(SCN)4(CN)(Bipy)2]n(2)，其中[AG5(SCN)4(Bipy)2]n(n+)阳离子柱连接了[AG5(SCN)4(Bipy)2]n(n+)阳离子柱，以及[(Me4N)Ag3(CN)4]n(3)与3重互穿三维(10，3)-g网络。并且都表现出高效的发光。
Three novel silver complexes, namely, [Ag5(CN)5(bipy)2]n (1) with a 1-D to 3-D architecture constructed through ligand-unsupported argentophilic interactions, [Ag5(SCN)4(CN)(bipy)2]n (2) with a 2-D interesting topology formed by cyanide groups linking [Ag5(SCN)4(bipy)2]n(n+) cationic columns, and [(Me4N)Ag3(CN)4]n (3) with 3-fold-interpenetrated 3-D 3-connected (10, 3)-g nets, have been solvothermally synthesized, and all exhibit efficient luminescence.