A new chiral N-heterocyclic carbene silver(I) cylinder: synthesis, crystal structure and catalytic properties.
A new chiral N-heterocyclic carbene silver(I) cylinder: synthesis, crystal structure and catalytic properties.
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DOI：
10.1039/c000793e
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发表时间：
2010-06
影响因子：
4.9
通讯作者：
Dehui Wang;Bingguang Zhang;Cheng He;Pengyan Wu;Chunying Duan
中科院分区：
文献类型：
--
作者：
Dehui Wang;Bingguang Zhang;Cheng He;Pengyan Wu;Chunying Duan
通过自组装制备了一种新型手性环状三咪唑啉盐及其手性N-杂环卡宾三银(I)圆柱笼，对多种希夫碱化合物的氰基甲硅烷基化反应具有尺寸选择性催化性能。
A new chiral cyclic triimidazoline salt and its chiral N-heterocyclic carbene trisilver(I) cylinder-like cage was prepared via self-assembly, with size-selective catalytic performance for the cyanosilylation of several Schiff-base compounds.