Photopolymerization Reactions Using the Photoinitiated Copper (I)-Catalyzed Azide-Alkyne Cycloaddition (CuAAC) Reaction
Photopolymerization Reactions Using the Photoinitiated Copper (I)-Catalyzed Azide-Alkyne Cycloaddition (CuAAC) Reaction
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DOI：
10.1002/adma.201203815
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发表时间：
2013-04-11
影响因子：
29.4
通讯作者：
Bowman, Christopher N.
中科院分区：
文献类型：
--
作者：
Gong, Tao;Adzima, Brian J.;Bowman, Christopher N.
首次使用 CuAAC 反应对多官能炔烃和叠氮化物单体进行本体光聚合，由低分子量、非粘性单体树脂成功进行。与其他传统的逐步生长本体光聚合相比，这种方法很容易提供交联的高玻璃化转变温度聚合物，该聚合物在整个聚合物结构中结合了三唑键，并且具有良好的时间控制。
The first bulk photopolymerization of multifunctional alkyne and azide monomers using the CuAAC reaction is successfully carried out from low molecular weight, nonviscous monomer resins. Compared to other traditional step-growth bulk photo polymerization, this approach readily provides crosslinked, high glass transition temperature polymers that incorporate triazole linkages throughout the polymer structure with great temporal control.