Design of BODIPY Dyes as Photosensitisers in Multicomponent Catalyst Systems for Light-Driven Hydrogen Production
Design of BODIPY Dyes as Photosensitisers in Multicomponent Catalyst Systems for Light-Driven Hydrogen Production
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DOI：
10.1002/chem.201501637
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发表时间：
2015-09-21
影响因子：
4.3
通讯作者：
Beweries, Torsten
中科院分区：
文献类型：
--
作者：
Dura, Laura;Ahrens, Johannes;Beweries, Torsten
本文研究了以四氢呋喃/水混合物为原料，由不同的硼二吡啶（BODIPY）染料、三乙胺和[{Pd(PPh3)Cl-2}(2)]组成的多组分体系在可见光下制氢。三种介甲基BODIPY染料表现出最好的活性和10天以上的长期稳定性，其中2,6-二碘衍生物表现出最好的性能。
A study of visible-light-driven hydrogen production using a multicomponent system consisting of different boron dipyrromethene (BODIPY) dyes, triethylamine and [{Pd(PPh3)Cl-2}(2)] from THF/water mixtures is presented. A trio of meso-mesityl BODIPY dyes display the best activities and long-term stabilities of more than ten days with the 2,6-diiodo derivative showing the best performance.