A simple and advantageous protocol for the oxidation of alcohols with, o-iodoxybenzoic acid (IBX)
A simple and advantageous protocol for the oxidation of alcohols with, o-iodoxybenzoic acid (IBX)
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DOI：
10.1021/ol026427n
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发表时间：
2002-08-22
期刊：
影响因子：
5.2
通讯作者：
Finney, NS
中科院分区：
文献类型：
--
作者：
More, JD;Finney, NS
描述了一种使用 IBX 氧化醇的高效且用户友好的程序。只需在悬浮 IBX 存在下加热醇溶液，然后过滤并除去溶剂即可得到相应羰基化合物的优异产率。我们用一组伯醇和仲醇底物说明了该过程，并注意到它允许氧化剂的回收和再利用。
An efficient, user-friendly procedure for the oxidation of alcohols using IBX is described. Simply heating a solution of the alcohol in the presence of suspended IBX followed by filtration and removal of the solvent gives excellent yields of the corresponding carbonyl compounds. We illustrate this procedure with a panel of primary and secondary alcohol substrates and note that it allows recycling and reuse of the oxidant.