STUDY ON TRIAZINE THIOLS .5. POLYMERIZATION OF 6-(4-VINYLBENZYL PROPYL) AMINO-1,3,5-TRIAZINE-2,4-DITHIOL ON COPPER PLATES AND THEIR CORROSION-RESISTANCE
STUDY ON TRIAZINE THIOLS .5. POLYMERIZATION OF 6-(4-VINYLBENZYL PROPYL) AMINO-1,3,5-TRIAZINE-2,4-DITHIOL ON COPPER PLATES AND THEIR CORROSION-RESISTANCE
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DOI：
10.1002/pol.1983.130211105
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发表时间：
1983-01-01
期刊：
影响因子：
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通讯作者：
NAKAMURA, Y
中科院分区：
文献类型：
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作者：
MORI, K;NAKAMURA, Y
一些单体吸附在硅胶、金属氧化物和金属硫酸盐等无机材料上的聚合反应已经被研究过(1)。然而，对吸附在金属表面或与金属表面反应的单体的聚合或共聚知之甚少。另一方面，为了提高与金属板的附着力，已经尝试了金属化合物如有机钛酸盐和硅酸盐与金属表面的反应，但由于这些化合物与金属表面的反应活性非常低，反应失败了。作者报告说，三嗪硫醇很容易与金属表面反应，使膜具有优异的附着力和保护表面免受腐蚀的能力（2-4）。本文介绍了用该反应制备可聚合乙烯基铜板的方法。研究了乙烯基在铜板上的聚合和接枝共聚，以保护铜表面免受腐蚀。
Polymerization of some monomers adsorbed on inorganic materials such as silica gel, metal oxides, and metal sulfates has been investigated previously (1). However, little is known of the polymerization or the copolymerization of monomers adsorbed on or reacted with metal surfaces. On the other hand, the reaction of metal compounds such as organic titanates and silicates with metal surfaces had already been tried in order to improve adhesion to metal plates, but the reaction failed since these compounds have very low reactivity with metal surfaces. The authors have reported that triazine thiols react easily with metal surfaces to give fims with excellent adhesion and ability to protect the surfaces against corrosion (2-4). In this article, the preparation of copper plates with polymerizable vinyl groups by this reaction is described. The polymerization and the graft copolymerization of vinyl groups on copper plates were investigated in order to protect the copper surface against corrosion.