A new synthesis of aldehydes by the palladium-catalyzed reaction of 2-pyridinyl esters with hydrosilanes

A new synthesis of aldehydes by the palladium-catalyzed reaction of 2-pyridinyl esters with hydrosilanes
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钯催化 2-吡啶酯与氢硅烷反应合成醛的新方法

DOI:
10.1055/s-2006-939058
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发表时间:
2006
期刊:
影响因子:
2
通讯作者:
N. Chatani
N. Chatani
中科院分区:
化学4区
文献类型:
--
作者:
J. Nakanishi;Hiroto Tatamidani;Y. Fukumoto;N. Chatani

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介绍了钯催化2-吡啶酯与氢硅烷反应合成醛类化合物的新方法。该反应适用于制备脂肪族、芳香族和α、β-不饱和醛。可耐受各种官能团,如氟、甲氧基、醛、缩醛和酯。
A new synthesis of aldehydes by the palladium-catalyzed reaction of 2-pyridinyl esters with hydrosilanes is described. The reaction is applicable to the preparation of aliphatic, aromatic, and α,β-unsaturated aldehydes. Various functional groups, such as fluoro, methoxy, aldehyde, acetal, and ester, are tolerated.