Acousto-optically modulated quantum cascade laser for high-temperature reacting systems thermometry
Acousto-optically modulated quantum cascade laser for high-temperature reacting systems thermometry
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DOI:
10.1364/ol.44.001435
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发表时间:
2019-03-15
期刊:
影响因子:
3.6
通讯作者:
Vasu, Subith S.
中科院分区:
文献类型:
--
作者:
Loparo, Zachary E.;Ninnemann, Erik;Vasu, Subith S.
We demonstrate time-resolved temperature measurements in shock-heated mixtures of carbon monoxide over a temperature range of 1000-1800 K for two pressure ranges, 2.0-2.9 atm and 7.6-10.7 atm, at rates up to 250 kHz using a single acousto-optically modulated quantum cascade laser with mid-infrared output spanning from 1975 to 2260 cm(-1). Measured temperatures were in excellent agreement with values determined by ideal shock relations, and the temperature profile after the passage of the reflected shock wave was found to be well-modeled by an isentropic compression assumption. Temperature measurements made with this setup are largely immune to effects of emissions and beam steering, making the diagnostic system well-suited for studying high-temperature gas-phase reactions of energetic materials such as octahydro-1,33,7-tetranitro-1,3,5,7-tetrazocine and hexahydro-1,3,5-trinitro-1,3,5-triazine. (C) 2019 Optical Society of America