Magnetism: Molecules to Materials V

Magnetism: Molecules to Materials V
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DOI：
10.1002/9783527620548
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发表时间：
2001-10
期刊：
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影响因子：
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通讯作者：
Joel S A Miller;M. Drillon
Joel S A Miller;M. Drillon
中科院分区：
其他
文献类型：
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作者：
Joel S A Miller;M. Drillon

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前言1阴离子双（二氯酸盐）金属酸盐的茂金属盐（Vasco Gama和Maria Teresa Duarte）。1.1简介。1.2基本结构基元。1.3固态结构与磁性。1.4总结与结论。参考文献2手性分子基磁体（Katsuya Inoue, Shin-ichi Ohkoshi, and Hiroyuki Imai）。2.1简介。2.2手性或非中心对称磁性材料的物理和光学性质。2.3氮氧化物-锰基手性磁体。2.4二维和三维氰化物桥接手性磁体。2.5 shg活性普鲁士蓝磁膜。2.6结论。参考文献3金属-双氰胺配合物的协同磁性行为（Jamie L. Manson）。3.1简介3.2“二元”α -M(dca)2磁体3.3 β -M(dca)2磁体3.4混合阴离子M(dca)（tcm）3.5聚合物2D (cat)M(dca)34As, Fe(bipy)33.6异眠性M(dca)2L磁体。3.7双氰磷素：双氰酰胺的含磷类似物。3.8结论和未来展望。参考文献4结合磁性和导电性的分子材料（Peter Day和Eugenio Coronado）。4.1简介。4.2导电分子基磁体的兴趣。4.3分子电荷转移盐中的磁性离子。4.4结论。参考文献。5镧系离子在分子交换耦合体系中的应用（Jean-Pascal Sutter and Myrtil L. Kahn）。5.1简介。5.2含Gd的分子化合物（III）。5.3 Ln（III）离子介导的超交换5.4含有一阶轨道动量的Ln（III）离子的交换偶联化合物5.5结束语参考文献6蒙特卡罗模拟：一种分析磁性的工具（Joan Cano和Yves Journaux）。6.1简介。6.2蒙特卡罗方法。6.3规则无限网络。6.4交替链。6.5有限系统。6.6精确定律与MC模拟。6.7一些复杂的例子。6.8结论与未来展望。参考文献。7茂金属基磁铁（Gordon T. Yee和Joel S. Miller）。7.1简介。7.2中性十甲基茂金属和十甲基茂金属阳离子与反磁性阴离子配对的电化学和磁性。7.3磁性电子转移盐的制备。7.4磁性ET盐的晶体结构。7.5四氰乙烯盐（方案7.2）。7.6二甲基双氰马酸盐和二乙基双氰马酸盐。7.7 2,3-二氯-5,6-二氰醌盐及相关化合物。7.8 2,3-二氰-1,4-萘醌盐。7.9 7,7,8,8-四氰-对喹诺二甲烷盐。7.10 2,5-二甲基-N，N'-二氰喹诺二亚胺盐。7.11 1,4,9,10-蒽四酮盐。7.12氰基和全氟甲基乙烯二硫酸盐。7.13苯二硫酸盐和乙烯二硫酸盐。7.14其他二硫酸盐实例。7.15二（三氟甲基）乙烯二硒酸镍盐。7.16支持铁磁偶联的其他受体7.17其他茂金属和相关物质作为供体，7.18 μ子自旋弛豫谱，7.19穆斯堡尔谱，7.20计算和中子衍射数据的自旋密度分布，7.21磁系统的维数和相变的附加证据，7.22 ET盐中磁耦合机制的争议，7.23趋势，7.24研究机会。参考文献。8磁性纳米多孔分子材料（Daniel Maspoch， Daniel Ruiz-Molina和Jaume Veciana）。8.1简介。8.2无机与分子杂化磁性纳米多孔材料。8.3磁性纳米多孔配位聚合物。8.4总结与展望。参考文献：9磁性普鲁士蓝类似物（米歇尔·弗达盖尔和格雷戈里·s·吉罗拉米）。9.1简介。9.2普鲁士蓝类似物（PBA），简史，合成和结构。9.3磁性普鲁士蓝（MPB）。9.4高TC普鲁士蓝（高居里温度的实验竞赛）。9.5展望与新趋势9.6结论：一棵300岁的“无机常绿树”参考文献。10标度理论应用于低维磁系统（Jean Souletie， Pierre Rabu和Marc Drillon）。10.1简介。10.2非临界标度：标度模型的其他解。10.3普适性类和低临界维数。10.4层状化合物中的相变。10.5铁磁海森堡链的描述。10.6自旋为1的Haldane链的应用。10.7结论。参考文献。索引。
Preface. 1 Metallocenium Salts of Radical Anion Bis(Dichalcogenate) Metalates (Vasco Gama and Maria Teresa Duarte). 1.1 Introduction. 1.2 Basic Structural Motifs. 1.3 Solid-state Structures and Magnetic Behavior. 1.4 Summary and Conclusions. References. 2 Chiral Molecule-Based Magnets (Katsuya Inoue, Shin-ichi Ohkoshi, and Hiroyuki Imai). 2.1 Introduction. 2.2 Physical and Optical Properties of Chiral or Noncentrosymmetric Magnetic Materials. 2.3 Nitroxide-manganese Based Chiral Magnets. 2.4 Two- and Three-dimensional Cyanide Bridged Chiral Magnets. 2.5 SHG-active Prussian Blue Magnetic Films. 2.6 Conclusion. References. 3 Cooperative Magnetic Behavior in Metal-Dicyanamide Complexes (Jamie L. Manson). 3.1 Introduction. 3.2 "Binary" alpha-M(dca)2 Magnets. 3.3 beta-M(dca)2 Magnets. 3.4 Mixed-anion M(dca)(tcm). 3.5 Polymeric 2D (cat)M(dca)34As, Fe(bipy)3. 3.6 Heteroleptic M(dca)2L Magnets. 3.7 Dicyanophosphide: A Phosphorus-containing Analog of Dicyanamide. 3.8 Conclusions and Future Prospects. References. 4 Molecular Materials Combining Magnetic and Conducting Properties (Peter Day and Eugenio Coronado). 4.1 Introduction. 4.2 Interest of Conducting Molecular-based Magnets. 4.3 Magnetic Ions in Molecular Charge Transfer Salts. 4.4 Conclusions. References. 5 Lanthanide Ions in Molecular Exchange Coupled Systems (Jean-Pascal Sutter and Myrtil L. Kahn). 5.1 Introduction. 5.2 Molecular Compounds Involving Gd(III). 5.3 Superexchange Mediated by Ln(III) Ions. 5.4 Exchange Coupled Compounds Involving Ln(III) Ions with a First-order Orbital Momentum. 5.5 Concluding Remarks. References. 6 Monte Carlo Simulation: A Tool to Analyse Magnetic Properties (Joan Cano and Yves Journaux). 6.1 Introduction. 6.2 Monte Carlo Method. 6.3 Regular Infinite Networks. 6.4 Alternating Chains. 6.5 Finite Systems. 6.6 Exact Laws versus MC Simulations. 6.7 Some Complex Examples. 6.8 Conclusions and Future Prospects. References. 7 Metallocene-based Magnets (Gordon T. Yee and Joel S. Miller). 7.1 Introduction. 7.2 Electrochemical and Magnetic Properties of Neutral Decamethylmetallocenes and Decamethylmetallocenium Cations Paired with Diamagnetic Anions. 7.3 Preparation of Magnetic Electron Transfer Salts. 7.4 Crystal Structures of Magnetic ET Salts. 7.5 Tetracyanoethylene Salts (Scheme 7.2). 7.6 Dimethyl Dicyanofumarate and Diethyl Dicyanofumarate Salts. 7.7 2,3-Dichloro-5,6-dicyanoquinone Salts and Related Compounds. 7.8 2,3-Dicyano-1,4-naphthoquinone Salts. 7.9 7,7,8,8-Tetracyano-p-quinodimethane Salts. 7.10 2,5-Dimethyl-N,N'-dicyanoquinodiimine Salts. 7.11 1,4,9,10-Anthracenetetrone Salts. 7.12 Cyano and Perfluoromethyl Ethylenedithiolato Metalate Salts. 7.13 Benzenedithiolates and Ethylenedithiolates. 7.14 Additional Dithiolate Examples. 7.15 Bis(trifluoromethyl)ethylenediselenato Nickelate Salts. 7.16 Other Acceptors that Support Ferromagnetic Coupling, but not Long-range Order above ~2K. 7.17 Other Metallocenes and Related Species as Donors. 7.18 Muon Spin Relaxation Spectroscopy. 7.19 Mossbauer Spectroscopy. 7.20 Spin Density Distribution from Calculations and Neutron Diffraction Data. 7.21 Dimensionality of the Magnetic System and Additional Evidence for a Phase Transition. 7.22 The Controversy Around the Mechanism of Magnetic Coupling in ET Salts. 7.23 Trends. 7.24 Research Opportunities. References. 8 Magnetic Nanoporous Molecular Materials (Daniel Maspoch, Daniel Ruiz-Molina, and Jaume Veciana). 8.1 Introduction. 8.2 Inorganic and Molecular Hybrid Magnetic Nanoporous Materials. 8.3 Magnetic Nanoporous Coordination Polymers. 8.4 Summary and Perspectives. References. 9 Magnetic Prussian Blue Analogs (Michel Verdaguer and Gregory S. Girolami). 9.1 Introduction. 9.2 Prussian Blue Analogs (PBA), Brief History, Synthesis and Structure. 9.3 Magnetic Prussian Blues (MPB). 9.4 High TC Prussian Blues (the Experimental Race to High Curie Temperatures). 9.5 Prospects and New Trends. 9.6 Conclusion: a 300 Years Old "Inorganic Evergreen". References. 10 Scaling Theory Applied to Low Dimensional Magnetic Systems (Jean Souletie, Pierre Rabu, and Marc Drillon). 10.1 Introduction. 10.2 Non-critical-scaling: the Other Solutions of the Scaling Model. 10.3 Universality Classes and Lower Critical Dimensionality. 10.4 Phase Transition in Layered Compounds. 10.5 Description of Ferromagnetic Heisenberg Chains. 10.6 Application to the Spin-1 Haldane Chain. 10.7 Conclusion. References. Index.