Comments on the article entitled “Additional remarks related with the discussion...” by J. C. Eriksson and A. I. Rusanov [Surf. Sci. 604 (2010) 1062–1063]

Comments on the article entitled “Additional remarks related with the discussion...” by J. C. Eriksson and A. I. Rusanov [Surf. Sci. 604 (2010) 1062–1063]
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对 J. C. Eriksson 和 A. I. Rusanov 题为“与讨论相关的附加评论”的文章的评论 [Surf. 604 (2010) 1062–1063]

DOI:
10.1016/j.susc.2010.12.020
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发表时间:
2011
期刊:
影响因子:
1.9
通讯作者:
E. Gutman
E. Gutman
中科院分区:
化学3区
文献类型:
--
作者:
E. Gutman

文献摘要

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U S 1()=TSS1()+γA+μ2NS21()(2)式中γ是“在界面切向工作的超额张力”,即式(1)中的项γda是偏导数,表示表面拉伸的机械可逆功。下标S表示表面过剩的能量、熵和摩尔数,μ2表示第二组分的化学势。
U s 1 ()= TSs 1 ()+ γA+ μ2ns 2 1 ()(2) where γ is “the excess tension operating in tangential directions in the interface”, ie the term γdA in Eq.(1) is a partial differential and presents a mechanical reversible work of surface stretching. Here the subscript s denotes the surface excess of the energy, entropy and number of moles, and μ2 is the chemical potential of the second component.