Homobenzotetramisole: An effective catalyst for kinetic resolution of aryl-cycloalkanols
Homobenzotetramisole: An effective catalyst for kinetic resolution of aryl-cycloalkanols
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DOI：
10.1021/ol703119n
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发表时间：
2008-03-20
期刊：
影响因子：
5.2
通讯作者：
Li, Ximin
中科院分区：
文献类型：
--
作者：
Birman, Vladimir B.;Li, Ximin
均苯并四咪唑（HBTM），一个以前报道的催化剂BTM的扩环类似物，显示出更高的催化活性和不同的结构选择性。它在仲苄醇的动力学拆分中表现出良好的对映选择性，但对2-芳基取代的环烷醇特别有效。
Homobenzotetramisole (HBTM), a ring-expanded analogue of the previously reported catalyst BTM, displays higher catalytic activity and a different structure-selectivity profile. It displays good enantioselectivities in kinetic resolution of secondary benzylic alcohols but is particularly effective for 2-aryl-substituted cycloalkanols.