The optical behavior of amorphous microribbons for hydroxy-naphthol based Schiff bases

The optical behavior of amorphous microribbons for hydroxy-naphthol based Schiff bases
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羟基萘酚席夫碱非晶微带的光学行为

DOI:
10.1016/j.jlumin.2016.12.050
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发表时间:
2017-05
影响因子:
3.6
通讯作者:
Yang Changying
Yang Changying
中科院分区:
物理与天体物理2区
文献类型:
--
作者:
Shen Ping;Liu Chunlin;Yang Wei;Liu Xuan;Du Jinya;Liu Yi;Yang Changying

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The optical behaviors of three hydroxy-naphthol based Schiff bases, L1, L2 and L3, in aggregated states in 1,4-dioxane (Diox) – H2O mixture, were investigated. The intermolecular hydrogen bond between luminogen and water resulted in the twisting of benzothiazole group, which is favorable for the assembly of organic molecules into J-aggregates. And also a bathochromic shift in absorption and enhancement of the fluorescence emission (aggregation-induced enhanced emission, AIEE) can be observed. L1 and L2 in Diox-H2O mixture with water volume fractions (fw) 95% assembled into microribbons with 40–50 nm thickness, twisted together to make amorphous supramolecular organogels. Whereas L3 assembled into needle-like nanorods with the thickness up to ~200 nm, consistence with its lower emission intensity compared to L1, L2 aggregates. Moreover, a drastic blue-shift and an enhancement of emission efficiency of L1-L3 were also observed in solid states with the morphology change from the crystalline to the amorphous state by grinding. It was found that L1 aggregates showed fluorescence switch-off sensing towards Cu2+, with higher selectivity and sensitivity compared to L1 in Diox solution.
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