Nickel-catalyzed alkenylative cross-coupling reaction of alkyl sulfides.
Nickel-catalyzed alkenylative cross-coupling reaction of alkyl sulfides.
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DOI：
10.1021/ja104155f
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发表时间：
2010-09
影响因子：
15
通讯作者：
K. Ishizuka;Hirofumi Seike;T. Hatakeyama;Masaharu Nakamura
中科院分区：
文献类型：
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作者：
K. Ishizuka;Hirofumi Seike;T. Hatakeyama;Masaharu Nakamura
以Ni（cod）（2）为催化剂，通过N-杂环卡宾配体SIPr，实现了烷基芳基硫醚与芳基Grignard试剂的交叉偶联反应，高产率地得到了烯基-芳基偶联产物.
A novel cross-coupling reaction of alkyl aryl sulfides with aryl Grignard reagents has been achieved to produce the alkenyl-aryl coupling products in high yields by using catalytic Ni(cod)(2) and a bulky N-heterocyclic carbene ligand, SIPr.