Radical reduction of aromatic azides to amines with triethylsilane
Radical reduction of aromatic azides to amines with triethylsilane
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DOI：
10.1021/jo060824k
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发表时间：
2006-07-21
影响因子：
3.6
通讯作者：
Zanardi, Giuseppe
中科院分区：
文献类型：
--
作者：
Benati, Luisa;Bencivenni, Giorgio;Zanardi, Giuseppe
在热条件下，在自由基引发剂的存在下，芳族叠氮化物对三乙基硅烷是惰性的，但在额外催化量的叔-十二烷基乙烷的存在下，它们以几乎定量的产率提供苯胺基硅烷和相应的苯胺。
Aromatic azides are inert toward triethylsilane under thermal conditions in the presence of a radical initiator, but in the presence of additional catalytic amounts of tert-do-decanethiol, they afford anilinosilanes and thence the corresponding anilines in virtually quantitative yields.