EFFICIENT PHOTOCHEMICAL REDUCTION OF CO2 TO CO BY VISIBLE-LIGHT IRRADIATION OF SYSTEMS CONTAINING RE(BIPY)(CO)3X OR RU(BIPY)32+-CO2+ COMBINATIONS AS HOMOGENEOUS CATALYSTS
EFFICIENT PHOTOCHEMICAL REDUCTION OF CO2 TO CO BY VISIBLE-LIGHT IRRADIATION OF SYSTEMS CONTAINING RE(BIPY)(CO)3X OR RU(BIPY)32+-CO2+ COMBINATIONS AS HOMOGENEOUS CATALYSTS
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DOI：
10.1039/c39830000536
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发表时间：
1983-01-01
影响因子：
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通讯作者：
ZIESSEL, R
中科院分区：
文献类型：
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作者：
HAWECKER, J;LEHN, JM;ZIESSEL, R
分别以Ru（bipy）_3 ~（2+）-Co ~（2+）或Re（bipy）（CO）_3X（X = Cl，Br）为均相催化剂，在（HOCH_2CH_2）_3N-二甲基甲酰胺中的CO_2溶液可见光照射下，可同时或选择性地光生CO_2。
Efficient photogeneration of either (CO + H2) simultaneously, or CO selectively, occurs on visible light irradiation of CO2 solutions in (HOCH2CH2)3N–dimethylformamide containing, respectively, Ru(bipy)32+–Co2+ combinations or the single component Re(bipy)(CO)3X (X = Cl, Br) as homogeneous catalysts.