Propenyl ethers. I. The synthesis of propenyl ether monomers
Propenyl ethers. I. The synthesis of propenyl ether monomers
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丙烯基醚。
DOI：
10.1002/pola.1993.080310616
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发表时间：
1993
期刊：
影响因子：
--
通讯作者：
K. D. Jo
中科院分区：
文献类型：
--
作者：
J. Crivello;K. D. Jo
通过醇与烯丙基卤的缩合，然后碱或过渡金属催化重排相应的烯丙基醚，可以容易地以高产率制备各种单官能、二官能和多官能丙烯基醚。它们的直接合成和阳离子紫外线固化的高反应性使这些单体对各种应用极具吸引力。这些单体的成功光聚合需要合成专门定制的鎓盐光引发剂。 © 1993 约翰威利父子公司。
A variety of mono-, di-, and multifunctional propenyl ethers were readily prepared in high yields by the condensation of alcohols with allyl halides followed by the base or transition metal-catalyzed rearrangement of the corresponding allyl ethers. Their straightforward synthesis and high reactivity in cationic UV curing make these monomers highly attractive for a variety of applications. The successful photopolymerization of these monomers has required the synthesis of specially tailored onium salt photoinitiators. © 1993 John Wiley & Sons, Inc.