Anion coordination by metallamacrocycles: a cryptand-like cavity
Anion coordination by metallamacrocycles: a cryptand-like cavity
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DOI：
10.1039/c2cc34061e
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发表时间：
2012-01-01
影响因子：
4.9
通讯作者：
Font-Bardia, Merce
中科院分区：
文献类型：
--
作者：
Escuer, Albert;Esteban, Jordi;Font-Bardia, Merce
{Ni-9(N-3)(9)}金属大环能够通过氢键相互作用在三角棱柱空腔中配位叠氮化物和卤化物阴离子。它提供了一个前所未有的自组装类穴状空腔的例子。
A {Ni-9(N-3)(9)} metallamacrocycle is able to coordinate azide and halide anions in trigonal prismatic cavities by means of H-bond interactions. It provides an unprecedented example of a self-assembled cryptand-like cavity.