Influence of monomer concentration and electrode conductivity on morphology of poly(o-anisidine) films

Influence of monomer concentration and electrode conductivity on morphology of poly(o-anisidine) films
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单体浓度和电极电导率对聚邻甲氧基苯胺薄膜形貌的影响

DOI:
10.1088/0022-3727/27/8/022
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发表时间:
1994
期刊:
影响因子:
--
通讯作者:
C. Agashe
C. Agashe
中科院分区:
--
文献类型:
--
作者:
A. Bedekar;S. Patil;R. Patil;C. Agashe

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用扫描电子显微镜研究了单体浓度和电极电导率对电化学沉积聚(邻氨基苯甲胺)薄膜形貌的影响。除了在较低的电导率电极和较低浓度的单体上,薄膜表现出纤维状的形态。单体浓度主要控制薄膜的反应和沉积速度;其效果可以通过各种类型的纤维图案化来观察,即网状、网状、蒸馏状、扇形等。纤维的数密度受电极导电性的影响。
The influence of monomer concentration and electrode conductivity on the morphology of electrochemically deposited poly (o-anisidine) films has been investigated using scanning electron microscopy. The films are found to exhibit a fibrillar morphology, except on lower conductivity electrodes and at lower concentrations of the monomer. The monomer concentration predominantly governs the rate of reaction and deposition of films; the effect of which is observed in terms of various types of patterning of fibres, namely anastomistic, reticulate, stillate, flabellate and so on. The number density of fibres is seen to be affected by the electrode conductivity.