Nickel-catalyzed cross-couplings of organosillicon reagents with unactivated secondary alkyl bromides

Nickel-catalyzed cross-couplings of organosillicon reagents with unactivated secondary alkyl bromides
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DOI:
10.1021/ja047433c
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发表时间:
2004-06-30
影响因子:
15
通讯作者:
Fu, GC
Fu, GC
中科院分区:
化学1区
文献类型:
--
作者:
Powell, DA;Fu, GC

文献摘要

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研究了金属催化有机硅化合物与烷基卤化物的交叉偶联反应。该方法值得注意的特性是其范围(二级亲电试剂),其高官能团相容性以及催化剂组分的空气稳定性。
A metal-catalyzed cross-coupling of organosilicon compounds with alkyl halides has been developed. Noteworthy attributes of the method are its scope (secondary electrophiles), its high functional-group compatibility, and the air stability of the catalyst components.