Modelling Development in Radical (Co)Polymerization of Multivinyl Monomers.
Modelling Development in Radical (Co)Polymerization of Multivinyl Monomers.
复制标题
多乙烯基单体自由基（共）聚合的模型开发
DOI：
10.1002/anie.202212235
复制
发表时间：
2023-01-26
影响因子：
16.6
通讯作者：
Wang, Wenxin
中科院分区：
文献类型：
--
作者：
Lyu, Jing;Li, Yinghao;Li, Zishan;Polanowski, Piotr;Jeszka, Jeremiasz K.;Matyjaszewski, Krzysztof;Wang, Wenxin
多乙烯基单体的自由基聚合（RP）为聚合物的拓扑结构控制提供了一种简便的解决方案，由于其在工业和学术上的重要意义而受到越来越多的关注。人们一直在努力了解其机理，这是调节材料结构的关键。建模技术已经成为一个强大的工具，可以提供详细的信息，聚合动力学是无法通过实验。许多出版物报道了MVMs的自由基聚合（FRP）和可逆失活自由基聚合（RDRP）的实验和建模的结合。本文简要介绍了最重要的建模技术及其在mvm FRP/RDRP中的应用。本文综述了建模和湿法实验的结合，为聚合物研究人员提供了宝贵的资源，并为未来MVMs实验优化和产品设计提供了新的思路。
Abstract Radical polymerization (RP) of multivinyl monomers (MVMs) provides a facile solution for manipulating polymer topology and has received increasing attention due to their industrial and academic significance. Continuous efforts have been made to understand their mechanism, which is the key to regulating materials structure. Modelling techniques have become a powerful tool that can provide detailed information on polymerization kinetics which is inaccessible by experiments. Many publications have reported the combination of experiments and modelling for free radical polymerization (FRP) and reversible‐deactivation radical polymerizations (RDRP) of MVMs. Herein, a minireview is presented for the most important modelling techniques and their applications in FRP/RDRP of MVMs. This review hopes to illustrate that the combination of modelling and wet experiments can be a great asset to polymer researchers and inspire new thinking for the future MVMs experiment optimization and product design.
登录
查看更多内容
影响因子：
1.5
作者：
Aguiar, Leandro G.;Goncalves, Miguel A. D.;Giudici, Reinaldo
通讯作者：
Giudici, Reinaldo
影响因子：
1.4
作者：
Aguiar, Leandro G.
通讯作者：
Aguiar, Leandro G.
影响因子：
3.2
作者：
BOOTS, HMJ;PANDEY, RB
通讯作者：
PANDEY, RB
影响因子：
5.5
作者：
Gao, Haifeng;Min, Ke;Matyjaszewski, Krzysztof
通讯作者：
Matyjaszewski, Krzysztof
影响因子：
5.5
作者：
Gao, Haifeng;Polanowski, Piotr;Matyjaszewski, Krzysztof
通讯作者：
Matyjaszewski, Krzysztof