Reversible Switching of the Luminescence of a Photoresponsive Gadolinium(III) Complex
Reversible Switching of the Luminescence of a Photoresponsive Gadolinium(III) Complex
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DOI：
10.1002/anie.201303137
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发表时间：
2013-08-12
影响因子：
16.6
通讯作者：
Ogo, Seiji
中科院分区：
文献类型：
--
作者：
Nakai, Hidetaka;Kitagawa, Kazuhiro;Ogo, Seiji
从蓝色到红色：研究了钆（III）配合物1的结构和发光性质。在室温下，通过交替光照射和O2暴露，呈现了1在THF中的发光的可逆切换，在此期间，发射颜色如图所示变化。1的光致磷光在这种行为中起着关键作用。
From blue to red: The structure and luminescence properties of the gadolinium (III) complex 1 were investigated. Reversible switching of the luminescence of 1 in THF at room temperature by alternating light irradiation and O2 exposure is presented, during which the emission color changes as shown in the picture. Light‐induced phosphorescence of 1 plays a key role in this behavior.