Acyclic cucurbit[n]urils capped with alkylene linkers: synthesis and molecular recognition properties
Acyclic cucurbit[n]urils capped with alkylene linkers: synthesis and molecular recognition properties
复制标题
DOI：
10.1080/10610278.2018.1539228
复制
发表时间：
2019-03-04
影响因子：
3.3
通讯作者：
Isaacs, Lyle
中科院分区：
文献类型：
--
作者：
Ganapati, Shweta;Isaacs, Lyle
我们报道了三个新的非环葫芦型受体的合成和表征，它们的特征是以亚烷基连接物(2a-2c)的形式存在的共价封端基团，我们假设这种基团与水中的烷基铵离子有更高的结合亲和力。主体2a-2c具有较低的水溶解度(
We report the synthesis and characterization of three new acyclic cucurbit[n]uril-type receptors that feature a covalent capping group in the form of an alkylene linker (2a - 2c) that we hypothesized would have higher binding affinity toward alkylammonium ions in water. Hosts 2a - 2c have lower aqueous solubility (