Chromatographic Separation of Trivalent Actinides by Using Tertiary Pyridine Resin with Methanolic Nitric Acid Solutions
Chromatographic Separation of Trivalent Actinides by Using Tertiary Pyridine Resin with Methanolic Nitric Acid Solutions
复制标题
叔吡啶树脂与甲醇硝酸溶液色谱分离三价锕系元素
DOI：
10.1080/18811248.2004.9715564
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发表时间：
2004
影响因子：
1.2
通讯作者：
M. Ozawa
中科院分区：
文献类型：
--
作者：
A. Ikeda;Tatsuya Suzuki;M. Aida;K. Otake;Y. Fujii;K. Itoh;T. Mitsugashira;M. Hara;M. Ozawa
Chromatographic separation of trivalent actinides (Am, Cm and Cf) was performed by using a tertiary pyridine resin embedded in silica beads with methanolic nitric acid solutions. The trivalent actinides were eluted from the resin column in the reverse order of atomic numbers (Cf-Cm-Am). Higher concentration of methanol in the mixed solution accelerated both the adsorption of these elements on the resin and the separability for these elements. Americium was clearly separated from Cm and Cf by using a 1 cm-ø × 10 cm-height column with a 60vol% of methanol/40 vol% of concentrated nitric acid mixed solution at ambient temperature.
