Development of a halide-free aluminium-based catalyst for the synthesis of cyclic carbonates from epoxides and carbon dioxide.
Development of a halide-free aluminium-based catalyst for the synthesis of cyclic carbonates from epoxides and carbon dioxide.
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DOI：
10.1002/chem.201404117
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发表时间：
2014-11
期刊：
影响因子：
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通讯作者：
J. Castro‐Osma;M. North;Xiao Wu
中科院分区：
文献类型：
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作者：
J. Castro‐Osma;M. North;Xiao Wu
对缩水甘油和二氧化碳合成碳酸甘油酯的反应动力学进行了研究。结果表明，在适宜的反应条件下，铝（salen）配合物4能够催化环氧化物转化为相应的环状碳酸酯，而不需要助催化剂。
Kinetic studies of the synthesis of glycerol carbonate from glycidol and carbon dioxide have been carried out. These showed that under suitable reaction conditions, bimetallic aluminium(salen) complex 4 is able to catalyse the conversion of epoxides into the corresponding cyclic carbonates without the need for a co-catalyst.