Iodine chemistry in the +1 oxidation state. I. The electronic spectra of OI−, HOI, and H2OI+
Iodine chemistry in the +1 oxidation state. I. The electronic spectra of OI−, HOI, and H2OI+
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+1 氧化态的碘化学 I. OI−、HOI 和 H2OI+ 的电子光谱。
DOI：
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发表时间：
1985
期刊：
影响因子：
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通讯作者：
B. L. Ford
中科院分区：
文献类型：
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作者：
J. Paquette;B. L. Ford
本文报道了水介质中次碘离子(OI-−)、次碘酸(HOI)及其共轭酸(H_2OI+)的电子光谱。+1氧化态的碘是由两个快速反应中的任何一个反应产生的，从而获得了OI−/HoI/H_2O~+在碱性介质中歧化成碘和碘酸盐，在酸性介质中歧化成碘和碘酸盐的光谱证据。这一结果与之前报道的HOI和H2O+的pKa值一致。
Electronic spectra are reported for the hypoiodite ion (OI−), hypoiodous acid (HOI), and its conjugate acid (H2OI+) in aqueous media. Iodine in the +1 oxidation state was produced by either of the two rapid reactionsorSpectroscopic evidence of the disproportionation of OI−/HOI/H2OI+ to iodide and iodate in basic media, and to iodine and iodate in acid media, was obtained. The results are consistent with previously reported values for the pKa of HOI and H2OI+.