Hydroxylamine Derivatives as Nitrogen-Radical Precursors in Visible-Light Photochemistry
Hydroxylamine Derivatives as Nitrogen-Radical Precursors in Visible-Light Photochemistry
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DOI：
10.1002/chem.201801655
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发表时间：
2018-08-22
影响因子：
4.3
通讯作者：
Leonori, Daniele
中科院分区：
文献类型：
--
作者：
Davies, Jacob;Morcillo, Sara P.;Leonori, Daniele
近年来，羟胺类化合物作为氮自由基的前体化合物在可见光光化学中得到了广泛的应用。它们在氧化还原化学中作为催化剂的能力推动了许多新的转化的发展。基本的机械方面，以及在含氮分子的制备的重要性将突出。
In recent years, hydroxylamines derivatives have been exploited as nitrogen-radical precursors in visible-light photochemistry. Their ability to serve as electrophores in redox chemistry has propelled the development of many novel transformations. Fundamental mechanistic aspects as well as the importance in the preparation of nitrogen-containing molecules will be highlighted.