Lithium redistribution around the crack tip of lithium-ion battery electrodes

Lithium redistribution around the crack tip of lithium-ion battery electrodes
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锂离子电池电极裂纹尖端周围锂的重新分布

DOI:
10.1016/j.scriptamat.2019.03.033
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发表时间:
2019-07-01
期刊:
影响因子:
6
通讯作者:
Fang,Daining
Fang,Daining
中科院分区:
材料科学1区
文献类型:
--
作者:
Yang,Le;Chen,Hao-Sen;Fang,Daining

文献摘要

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Silicon film with pre-crack was used to study the coupling effect of stress and electrochemical field around the crack tip. The in-situ experiments were established to monitor the crack to realize the stress concentration around the crack and simultaneously prevent the crack initiation. The ex-situ Auger electron spectroscopy experiments shown the remarkably Li redistributed phenomenon around the crack tip. Furthermore, the fully coupled finite element method was used to reveal the fundamental mechanisms of the Li gathering effect and the stress relaxation phenomenon around the crack tip.