Recent developments in copper-catalyzed reactions of diazo compounds
Recent developments in copper-catalyzed reactions of diazo compounds
复制标题
铜催化重氮化合物反应的最新进展
DOI：
10.1039/c2cc34406h
复制
发表时间：
2012-01-01
影响因子：
4.9
通讯作者：
Wang, Jianbo
中科院分区：
文献类型：
--
作者：
Zhao, Xia;Zhang, Yan;Wang, Jianbo
Copper-catalyzed reaction of diazo compounds generates copper carbene intermediates that undergo diverse transformations. In recent years, the selectivity and efficiency of these important conversions have been further improved. In particular, breakthroughs have been made in catalytic asymmetric polar X-H bond insertion reactions. Moreover, novel transformations based on copper carbene, namely copper-catalyzed cross-couplings of diazo compounds, have emerged as powerful methods for carbon-carbon bond formations. This feature article summarizes the most recent developments in this area.
