Complementary thin-layer chromatographic separations of some polyhedral borane anions and their derivatives
Complementary thin-layer chromatographic separations of some polyhedral borane anions and their derivatives
复制标题
一些多面体硼烷阴离子及其衍生物的互补薄层色谱分离
DOI：
10.1016/s0021-9673(00)83809-1
复制
发表时间：
1975
影响因子：
4.1
通讯作者：
R. Sneath
中科院分区：
文献类型：
--
作者：
G. Wellum;E. Tolpin;Linda P. Andersen;R. Sneath
阴离子硼烷衍生物已被分离使用离子交换和分配薄层色谱系统。硼烷化合物在离子交换体系中的RF级近似为分配体系的RF级的倒数。具有相似取代基的B10H102−和B12H122−的衍生物表现出优异的分离，并且有证据表明这些系统可以分辨二取代B10H102−的一些几何异构体。
Anionic borane derivatives have been separated using ion-exchange and partition thin-layer chromatographic systems. TheRForder of the borane compounds in the ion-exchange systems was approximately the inverse of that for the partition systems. Derivatives of B10H102−and B12H122−with similar substituents showed excellent separation, and there is evidence that these systems can resolve some geometrical isomers of disubstituted B10H102−.