Ferrocene-Supported Compartmental Ligands for the Assembly of 3d/4f Complexes
Ferrocene-Supported Compartmental Ligands for the Assembly of 3d/4f Complexes
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DOI：
10.1021/acsomega.0c00654
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发表时间：
2020-04
期刊：
影响因子：
4.1
通讯作者：
A. Chakraborty;Joydev Acharya;V. Chandrasekhar
中科院分区：
文献类型：
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作者：
A. Chakraborty;Joydev Acharya;V. Chandrasekhar
位置特异性配位配体，也称为隔室配体，已被用于制备异金属配合物。这些配体具有特定的结合部位，可以将不同的金属离子包裹在它们的配位口袋中。这种空间配位体已被广泛用于制备在分子磁学中有应用的异金属3D/4F络合物。本文综述了我们在利用二茂铁基室间配体制备异金属3D/4F配合物方面所做的工作，其中一些是单分子或单离子磁体。
Site-specific coordination ligands, also known as compartmental ligands, have been used for the preparation of heterometallic complexes. These ligands, by virtue of possessing specific binding sites, can encapsulate different metal ions in their coordination pockets. Such compartmental ligands have been widely used for the preparation of heterometallic 3d/4f complexes which have applications in molecular magnetism. This Review summarizes our efforts in the use of ferrocene-based compartmental ligands for the preparation of heterometallic 3d/4f complexes, some of which are single-molecule or single-ion magnets.