An n.m.r. study of FeH(dmpe)2(BH4)[dmpe = 1,2-bis(dimethylphosphino)ethane]–an iron complex containing amonodentate borohydrid ligand
An n.m.r. study of FeH(dmpe)2(BH4)[dmpe = 1,2-bis(dimethylphosphino)ethane]–an iron complex containing amonodentate borohydrid ligand
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FeH(dmpe)2(BH4)[dmpe = 1,2-双(二甲基膦基)乙烷]——含有单齿硼氢化物配体的铁配合物的核磁共振研究
DOI：
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发表时间：
1984
期刊：
影响因子：
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通讯作者：
L. Field
中科院分区：
文献类型：
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作者：
M. Baker;L. Field
在络合物FeH（dmpe）2（BH 4）[dmpe = 1，2-双（二甲基膦基）乙烷]中BH 4与铁的单氢桥连接是硼氢化物与铁的配位类型的首次报道;详细的n.m.r.研究表明，连接到硼原子上的桥连和端接氢原子容易交换。
The single-hydrogen bridge attachment of BH4 to iron in the complex FeH(dmpe)2(BH4)[dmpe = 1,2-bis(dimethylphosphino)ethane] is the first reported occurrence of that type of co-ordination of borohydride to iron; a detailed n.m.r. study has demonstrated the facile exchange of the bridging and termibal hydrogen atoms attached to the boron atom.