Microflow Radical Carboaminoxylations with a Novel Alkoxyamine
Microflow Radical Carboaminoxylations with a Novel Alkoxyamine
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DOI：
10.1021/ol900713d
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发表时间：
2009-06-04
期刊：
影响因子：
5.2
通讯作者：
Ryu, Ilhyong
中科院分区：
文献类型：
--
作者：
Wienhoefer, Inga C.;Studer, Armido;Ryu, Ilhyong
本文描述了用新型烷氧胺A生成B型加合物，对各种烯烃进行高效的热自由基羧基化反应。据报道，这些自由基加成反应可以在微流反应系统中进行。与传统的间歇反应装置相比，在类似的条件下，使用微流系统进行羧甲酰化反应可获得显著更高的产率。
Highly efficient thermal radical carboaminoxylations of various olefins by using the novel alkoxyamine A to give adducts of type B are described. It is reported that these radical addition reactions can be performed in a microflow reaction system. As compared to conventional batch reaction setup, significantly higher yields are obtained by running carboaminoxylations using the microflow system under analogous conditions.