Synthesis and thermotropic behavior of simple new glucolipid amides
Synthesis and thermotropic behavior of simple new glucolipid amides
复制标题
DOI：
10.1080/07328300701252565
复制
发表时间：
2007-01-01
影响因子：
1
通讯作者：
Mackenzie, Grahame
中科院分区：
文献类型：
--
作者：
Chambert, Stephane;Doutheau, Alain;Mackenzie, Grahame
The coupling reaction of 3,4,6-tri-O-acetyl-alpha-D-glucopyranoside 2-O-lactone 1 (alpha-CMGL) with two kinds of lipophilic amines, aminosteroids and fatty amines, efficiently yielded, after deprotection, the corresponding free alpha-glucolipid amides. The latter family of compounds exhibited good thermal stability, allowing the higher homologs having longer linear fatty chains or saturated steroids to possess lamellar smectic A phases.
