Three-Component Chlorophosphinoylation of Alkenes via Anodically Coupled Electrolysis
Three-Component Chlorophosphinoylation of Alkenes via Anodically Coupled Electrolysis
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DOI：
10.1055/s-0039-1689934
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发表时间：
2019-06-01
期刊：
影响因子：
2
通讯作者：
Lin, Song
中科院分区：
文献类型：
--
作者：
Lu, Lingxiang;Fu, Niankai;Lin, Song
我们报告了简单烯烃氯代膦酰化电催化方案的开发。在电驱动和锰催化剂介导下，异双官能化反应以高效率和区域选择性发生。循环伏安法数据与基于阳极耦合电解的机械情况一致，其中两种不同的自由基中间体的生成同时发生在阳极上并且均由锰催化剂介导。
We report the development of an electrocatalytic protocol for the chlorophosphinoylation of simple alkenes. Driven by electricity and mediated by a Mn catalyst, the heterodifunctionalization reaction takes place with high efficiency and regioselectivity. Cyclic voltammetry data are consistent with a mechanistic scenario based on anodically coupled electrolysis in which the generation of two distinct radical intermediates occur simultaneously on the anode and are both mediated by the Mn catalyst.