General theory of charge regulation within the Poisson-Boltzmann framework: Study of a sticky-charged wall model
General theory of charge regulation within the Poisson-Boltzmann framework: Study of a sticky-charged wall model
复制标题
DOI：
10.1063/1.5095966
复制
发表时间：
2019-05-21
影响因子：
4.4
通讯作者：
Frydel, Derek
中科院分区：
文献类型：
--
作者：
Frydel, Derek
这项工作介绍了一个粘性电荷壁模型作为一个简单而直观的表示电荷调节。在平均场水平的描述内实现，该模型修改边界条件而不影响电解质的基本泊松-玻尔兹曼（PB）方程。采用各种修改的PB方程，我们能够评估电解质的各种结构细节如何影响电荷调节。由AIP Publishing授权出版。
This work introduces a sticky-charge wall model as a simple and intuitive representation of charge regulation. Implemented within the meanfield level of description, the model modifies the boundary conditions without affecting the underlying Poisson-Boltzmann (PB) equation of an electrolyte. Employing various modified PB equations, we are able to assess how various structural details of an electrolyte influence charge regulation. Published under license by AIP Publishing.