Kinetic analysis of oligo(C) formation from the 5′-monophosphorimidazolide of cytidine with Pb(II) ion catalyst at 10-75°C

Kinetic analysis of oligo(C) formation from the 5′-monophosphorimidazolide of cytidine with Pb(II) ion catalyst at 10-75°C
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DOI:
10.1007/s11084-006-9063-0
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发表时间:
2007-04-01
影响因子:
2
通讯作者:
Maeda, Jun
Maeda, Jun
中科院分区:
物理与天体物理4区
文献类型:
--
作者:
Kawamura, Kunio;Maeda, Jun

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在 Pb(II) 离子催化剂存在下,研究了在 Pb(II) 离子催化剂存在下,从胞苷 (ImpC) 的 5'-单磷咪唑化物形成寡聚胞苷酸 (oligo(Q)) 的速率常数的温度依赖性。寡聚(C) 形成的速率常数按照 2 聚体形成的顺序增加。
The temperature dependence of the rate constants for the formation of oligocytidylate (oligo(Q) from the 5'-monophosphorimidazolide of cytidine (ImpC) in the presence of Pb(II) ion catalyst has been investigated at 10-75 degrees C. The rate constants for the formation of oligo(C) increased in the order of the formation of 2-mer