Azido-mediated systems showing different magnetic behaviors.
Azido-mediated systems showing different magnetic behaviors.
复制标题
DOI：
10.1039/b718581m
复制
发表时间：
2009-01
影响因子：
46.2
通讯作者：
Yong-Fei Zeng;Xin Hu;Fu‐Chen Liu;X. Bu
中科院分区：
文献类型：
--
作者：
Yong-Fei Zeng;Xin Hu;Fu‐Chen Liu;X. Bu
叠氮基作为一种桥连配体在磁性分子材料的构建中得到了广泛的应用，引起了人们的极大兴趣。本教程的审查是集中在叠氮金属化合物的研究与他们的磁性化学和由八个主要部分。第一部分介绍了叠氮配合物的基本情况，并介绍了叠氮配合物的磁结构相关性研究的一些重要结果，这些结果将在后面的章节中介绍。接下来的六个部分概述了叠氮介导的铁磁体，亚铁磁体，倾斜（弱）铁磁体，反铁磁体，单分子磁体（SMM）和单链磁体（SCM），和超磁体。最后一部分是结论，并对叠氮基磁性材料的研究前景进行了展望。
Azido has been one of the well used bridging ligands in the construction of magnetic molecule materials, which has stimulated considerable interest in magnetochemistry. This tutorial review is concentrated on the study of azido metal compounds with their magnetochemistry and consists of eight main sections. The first section offers an introduction to azido complexes and some important results obtained from magneto-structural correlation in azido complexes which will be referred to in the following sections. The next six sections give overviews of azido-mediated ferromagnets, ferrimagnets, canted (weak) ferromagnets, antiferromagnets, single molecule magnets (SMMs) and single chain magnets (SCMs), and metamagnets. The last section is the conclusion and gives a perspective of azido-mediated magnets.