PHOTOREDOX CATALYSIS BY [Ru(bpy)3]2+ TO TRIGGER TRANSFORMATIONS OF ORGANIC MOLECULES. ORGANIC SYNTHESIS USING VISIBLE-LIGHT PHOTOCATALYSIS AND ITS 20th CENTURY ROOTS
PHOTOREDOX CATALYSIS BY [Ru(bpy)3]2+ TO TRIGGER TRANSFORMATIONS OF ORGANIC MOLECULES. ORGANIC SYNTHESIS USING VISIBLE-LIGHT PHOTOCATALYSIS AND ITS 20th CENTURY ROOTS
复制标题
DOI：
10.1135/cccc2011078
复制
发表时间：
2011-01-01
影响因子：
--
通讯作者：
Teply, Filip
中科院分区：
文献类型：
--
作者：
Teply, Filip
由光引发的反应构成了化学家可用的独特合成方法的宝库。利用可见光与敏化染料结合的光诱导氧化还原过程提供了在有机合成领域中有用的多种催化转化。最近的文献充分表明，这一准备工具箱正在大幅扩大。本文综述了[Ru（bpy）（3）]（2+）在光氧化还原催化领域的历史和现状。优雅的例子，从最近的文献文件的重要性，这一快速发展的研究领域。光氧化还原化学也成为化学生物学和材料化学中一种很有前途的成键和断键工具。有96篇参考文献。
Reactions triggered by light constitute a treasure trove of unique synthetic methods that are available to chemists. Photoinduced redox processes using visible light in conjunction with sensitizing dyes offer a great variety of catalytic transformations useful in the realm of organic synthesis. The recent literature amply shows that this preparative toolbox is expanding substantially. This review discusses historical and contemporary work in the area of photoredox catalysis with [Ru(bpy)(3)](2+). Elegant examples from the most recent literature document the importance of this fast developing area of research. The photoredox chemistry has also emerged as a promising bond-making and bond-breaking tool for chemical biology and materials chemistry. A review with 96 references.