Diketopyrrolopyrrole-Diketopyrrolopyrrole-Based Conjugated Copolymer for High-Mobility Organic Field-Effect Transistors
Diketopyrrolopyrrole-Diketopyrrolopyrrole-Based Conjugated Copolymer for High-Mobility Organic Field-Effect Transistors
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DOI：
10.1021/ja308211n
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发表时间：
2012-10-10
影响因子：
15
通讯作者：
Patil, Satish
中科院分区：
文献类型：
--
作者：
Kanimozhi, Catherine;Yaacobi-Gross, Nir;Patil, Satish
在这篇通讯中，我们报道了一种新型的二酮基吡咯并吡咯-二酮基吡咯并吡咯（DPP-DPP）共轭共聚物的合成及其在高迁移率有机场效应晶体管中的应用。DPP与DPP的共聚产生具有优异性能的共聚物，例如扩展吸收特性（高达类似于1100 nm）和>1 cm（2）V-1 s（-1）的场效应电子迁移率值。这种新型DPP-DPP共聚物的合成与具有极高电子迁移率的晶体管的展示相结合，使得这项工作朝着在有机光电子学的一般领域中应用的新的DPP-DPP共聚物家族迈出了重要的一步。
In this communication, we report the synthesis of a novel diketopyrrolopyrrole-diketopyrrolopyrrole (DPP-DPP)-based conjugated copolymer and its application in high-mobility organic field-effect transistors. Copolymerization of DPP with DPP yields a copolymer with exceptional properties such as extended absorption characteristics (up to similar to 1100 nm) and field-effect electron mobility values of >1 cm(2) V-1 s(-1). The synthesis of this novel DPP-DPP copolymer in combination with the demonstration of transistors with extremely high electron mobility makes this work an important step toward a new family of DPP-DPP copolymers for application in the general area of organic optoelectronics.