Cylindrical Micelles of Controlled Length with a π-Conjugated Polythiophene Core via Crystallization-Driven Self-Assembly
Cylindrical Micelles of Controlled Length with a π-Conjugated Polythiophene Core via Crystallization-Driven Self-Assembly
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DOI：
10.1021/ja202408w
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发表时间：
2011-06-15
影响因子：
15
通讯作者：
Manners, Ian
中科院分区：
文献类型：
--
作者：
Patra, Sanjib K.;Ahmed, Rumman;Manners, Ian
区域规则聚噻吩型嵌段共聚物poly(3-hexylthiophene)-b-poly(dimethylsiloxane)的溶液自组装产生了具有结晶P3HT核的圆柱形胶束。以种子胶束为引发剂，通过结晶驱动自组装制备了长度可控的单分散纳米管。
Solution self-assembly of the regioregular polythiophene-based block copolymer poly(3-hexylthiophene)-b-poly(dimethylsiloxane) yields cylindrical micelles with a crystalline P3HT core. Monodisperse nanocylinders of controlled length have been prepared via crystallization-driven self-assembly using seed micelles as initiators.