Fine tuning of intra-lattice electron transfers through site doping in tetraoxolene-bridged iron honeycomb layers
Fine tuning of intra-lattice electron transfers through site doping in tetraoxolene-bridged iron honeycomb layers
复制标题
通过四氧乙烯桥联铁蜂窝层中的位点掺杂微调晶格内电子转移
DOI：
10.1039/d0cc03808c
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发表时间：
2020
影响因子：
4.9
通讯作者：
Miyasaka Hitoshi
中科院分区：
文献类型：
--
作者：
Sekine Yoshihiro;Chen Jian;Eguchi Naoki;Miyasaka Hitoshi
晶格内多重电子转移的精确控制在四氧杂环戊烯桥接的Fe蜂窝层系统的溶剂化和去溶剂化物种中得到了证明，（NPr 4）2[Fe 2（Cl 2An）3]·（solv）（Cl 2Ann − = 2，5-dichloro-3，6-dihydroxy-1，4-benzoquinonate; NPr 4 + =四丙基铵阳离子），通过使用X = Br或F的X2 Ann −单元对Cl 2Ann −桥接单元进行位点掺杂。
The precise control of intra-lattice multiple electron transfers was demonstrated in the solvated and desolvated species of the tetraoxolene-bridged Fe honeycomb layer system, (NPr4)2[Fe2(Cl2An)3]·(solv) (Cl2Ann− = 2,5-dichloro-3,6-dihydroxy-1,4-benzoquinonate; NPr4+ = tetrapropylammonium cation), by the site-doping of the Cl2Ann− bridging unit using X2Ann− units with X = Br or F.