Pd-Catalyzed Oxidative Cross-Coupling of Perfluoroarenes with Aromatic Heterocycles
Pd-Catalyzed Oxidative Cross-Coupling of Perfluoroarenes with Aromatic Heterocycles
复制标题
Pd 催化全氟芳烃与芳香杂环的氧化交叉偶联
DOI：
10.1021/ja106046p
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发表时间：
2010-09-22
影响因子：
15
通讯作者：
Zhang, Xingang
中科院分区：
文献类型：
--
作者：
He, Chun-Yang;Fan, Shilu;Zhang, Xingang
A straightforward and practical method for direct Pd(OAc)(2)-catalyzed oxidative cross-coupling of electron-deficient perfluoroarenes with aromatic heterocycles has been developed. Because of its low catalyst loading (2.5 mol %), high reaction efficiency, good chemo- and regioselectivity, and excellent functional-group compatibility, this protocol provides a useful and operationally simple access to perfluoroarene thiophene structures of interest in functional materials for electronic devices.
