THE STEREOSELECTIVE MICHAEL REACTION BETWEEN SILYL ENOL ETHERS AND α,β-UNSATURATED KETONES BY THE USE OF TRITYL PERCHLORATE AS A CATALYST
THE STEREOSELECTIVE MICHAEL REACTION BETWEEN SILYL ENOL ETHERS AND α,β-UNSATURATED KETONES BY THE USE OF TRITYL PERCHLORATE AS A CATALYST
复制标题
高氯酸三苯甲基酯催化硅烯醇醚与α,β-不饱和酮的立体选择性迈克尔反应
DOI：
10.1246/cl.1986.1017
复制
发表时间：
1986
影响因子：
1.6
通讯作者：
S. Kobayashi
中科院分区：
文献类型：
--
作者：
T. Mukaiyama;M. Tamura;S. Kobayashi
在催化量的三苯甲基高氯酸盐存在下，甲硅烷基烯醇醚与α，β-不饱和酮反应，得到了具有良好选择性的Michael加成物。
The Michael adducts are obtained with good to excellent ul selectivity by treating silyl enol ethers with α,β-unsaturated ketones in the presence of a catalytic amount of trityl perchlorate.