Synthesis of conjugated bisallenes by cooperative Cu/Pd-catalysed borylallenylation of 2-trifluoromethyl-1,3-enynes
Synthesis of conjugated bisallenes by cooperative Cu/Pd-catalysed borylallenylation of 2-trifluoromethyl-1,3-enynes
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通过铜/钯协同催化 2-三氟甲基-1,3-烯炔的硼基丙二烯化合成共轭双联烯。
DOI：
10.1039/d2cc03745a
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发表时间：
2022-10-26
影响因子：
4.9
通讯作者：
Fu，Yao
中科院分区：
文献类型：
--
作者：
Yu，Shang-Hai;Gong，Tian-Jun;Fu，Yao
A cooperative Cu/Pd-catalysed borylallenylation of 2-trifluoromethyl-1,3-enynes with propargylic carbonates under mild reaction conditions was developed. This method provides facile and efficient access to conjugated bisallenes with a broad range of functional groups. Both aromatic and aliphatic 1,3-enynes can be utilized in this transformation to give the corresponding multi-substituted conjugated bisallenes.
