Recent Breakthroughs in P 4 Chemistry: Towards Practical, Direct Transformations into P 1 Compounds
Recent Breakthroughs in P 4 Chemistry: Towards Practical, Direct Transformations into P 1 Compounds
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P 4 化学的最新突破：迈向实用、直接转化为 P 1 化合物
DOI：
10.1002/ange.202205019
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发表时间：
2022
影响因子：
--
通讯作者：
Scott D
中科院分区：
文献类型：
--
作者：
Scott D
几十年来，学术研究人员一直在深入研究白磷（P4）的化学性质，希望开发出将其转化为有用的含磷产品的直接方法。这将绕过目前工业所依赖的危险的多步骤程序。然而，尽管在学术上有趣的p4活化反应已经得到了很好的确立，但将其细化为有用的、通用的合成程序仍然遥不可及。然而，就在最近，一系列独立的报告已经开始改变这种状况。每个都展示了如何使用相对简单和实用的合成方法直接从p4中获得学术上或工业上相关的p1化合物，在“一个锅”中甚至以催化的方式。这些报告标志着p4化学领域的一个重大变化，并表明它可能从一个主要的学术兴趣领域转变为一个具有真正合成相关性的领域。
For several decades, academic researchers have been intensively studying the chemistry of white phosphorus (P4) in the hope of developing direct methods for its transformation into useful P‐containing products. This would bypass the hazardous, multistep procedures currently relied on by industry. However, while academically interesting P4activation reactions have become well established, their elaboration into useful, general synthetic procedures has remained out of reach. Very recently, however, a series of independent reports has begun to change this state of affairs. Each shows how relatively simple and practical synthetic methods can be used to access academically or industrially relevant P1compounds from P4directly, in “one pot” or even in a catalytic fashion. These reports mark a step change in the field of P4chemistry, and suggest its possible transition from an area of largely academic interest to one with the promise of true synthetic relevance.