Effect of coadsorbent properties on the photovoltaic performance of dye-sensitized solar cells

Effect of coadsorbent properties on the photovoltaic performance of dye-sensitized solar cells
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DOI:
10.1039/c0cc04999a
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发表时间:
2011-01-01
影响因子:
4.9
通讯作者:
Park, Taiho
Park, Taiho
中科院分区:
化学2区
文献类型:
--
作者:
Lim, Jongchul;Kwon, Young Soo;Park, Taiho

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在染料敏化太阳能电池(DSCs)中,硬脂酸作为共吸附剂,具有低的偶极矩和高的溶解度,减缓了染料在TiO2层上的竞争锚定过程中的吸附速度,从而增加了强结合染料在TiO2层上的含量。这使得J(SC)和DSC的功率转换效率都提高了约25%,即使染料覆盖率要低得多。
Stearic acid as a coadsorbent, which has a low dipole moment and high solubility, retarded the rate of dye adsorption during the competitive anchoring process on the TiO(2) layer in dye-sensitized solar cells (DSCs), thereby increasing the content of strongly bound dye on the TiO(2) surface. This resulted in an approximately 25% improvement in both J(SC) and the power conversion efficiency of the DSCs, even for much lower dye coverage.