Network formation mechanisms in conjugated microporous polymers
Network formation mechanisms in conjugated microporous polymers
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DOI：
10.1039/c4py00647j
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发表时间：
2014-01-01
影响因子：
4.6
通讯作者：
Adams, Dave J.
中科院分区：
文献类型：
--
作者：
Laybourn, Andrea;Dawson, Robert;Adams, Dave J.
我们详细讨论了形成的高度微孔聚合物，CMP-1，主要通过Sonogashira Hagihara耦合形成的机制。我们展示了微孔随时间的变化，并讨论了炔均偶联对微孔的重要性。
We discuss in detail the mechanism of formation of a highly microporous polymer, CMP-1, formed mainly via Sonogashira-Hagihara coupling. We demonstrate how the microporosity evolves with time, and discuss the importance of alkyne homo-coupling on the microporosity.